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Abstract
Eugenol is a liquid phenolic compound accessible from renewable resources such as clove or cinnamon, by lignin degradation or by chemical synthesis [1]. Many monomers and their corresponding polymers have been prepared from eugenol [2]. Here, we perform the epoxidation of the double bond to obtain the corresponding liquid epoxide, namely 2-methoxy-4-(oxiran-2-ylmethyl)phenol (epoxyeugenol, EE) in a single step, and test this monomer in the copolymerization with bisphenol A diglycidyl ether (DGEBA).
In particular, we studied the polymerization reaction with 1-methylimidazol and with K54 as initiators using isothermal and dynamic differential scanning calorimetry to determine activation energies and cure rates for different formulations. The thermal properties of the resulting thermoset materials are also described.
References
[1] Zhang C., Xue J., Yang X., Ke Y., Ou R., Wang Y., Madbouly S. A., Wang Q. Prog. Polym. Sci. 2022, 125, 101473.
[2] Morales-Cerrada R. Molina-Gutierrez S., Lacroix-Desmazes P., Caillol S. Biomacromolecules 2021, 22, 3625–3648.
In particular, we studied the polymerization reaction with 1-methylimidazol and with K54 as initiators using isothermal and dynamic differential scanning calorimetry to determine activation energies and cure rates for different formulations. The thermal properties of the resulting thermoset materials are also described.
References
[1] Zhang C., Xue J., Yang X., Ke Y., Ou R., Wang Y., Madbouly S. A., Wang Q. Prog. Polym. Sci. 2022, 125, 101473.
[2] Morales-Cerrada R. Molina-Gutierrez S., Lacroix-Desmazes P., Caillol S. Biomacromolecules 2021, 22, 3625–3648.
Originalsprache | englisch |
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Publikationsstatus | Veröffentlicht - 4 Sept. 2023 |
Veranstaltung | Polymer Meeting 15 - Bratislava, Slowakei Dauer: 4 Sept. 2023 → 7 Sept. 2023 https://pm15.sav.sk/ |
Konferenz
Konferenz | Polymer Meeting 15 |
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Kurztitel | PM15 |
Land/Gebiet | Slowakei |
Ort | Bratislava |
Zeitraum | 4/09/23 → 7/09/23 |
Internetadresse |
Fields of Expertise
- Advanced Materials Science
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