Copolymerization of epoxyeugenol and bisphenol A diglycidyl ether

Johanna Lang, Johanna Uher, Susanne Maria Fischer, Christian Slugovc

Publikation: KonferenzbeitragPosterBegutachtung

Abstract

Eugenol is a liquid phenolic compound accessible from renewable resources such as clove or cinnamon, by lignin degradation or by chemical synthesis [1]. Many monomers and their corresponding polymers have been prepared from eugenol [2]. Here, we perform the epoxidation of the double bond to obtain the corresponding liquid epoxide, namely 2-methoxy-4-(oxiran-2-ylmethyl)phenol (epoxyeugenol, EE) in a single step, and test this monomer in the copolymerization with bisphenol A diglycidyl ether (DGEBA).
In particular, we studied the polymerization reaction with 1-methylimidazol and with K54 as initiators using isothermal and dynamic differential scanning calorimetry to determine activation energies and cure rates for different formulations. The thermal properties of the resulting thermoset materials are also described.

References
[1] Zhang C., Xue J., Yang X., Ke Y., Ou R., Wang Y., Madbouly S. A., Wang Q. Prog. Polym. Sci. 2022, 125, 101473.
[2] Morales-Cerrada R. Molina-Gutierrez S., Lacroix-Desmazes P., Caillol S. Biomacromolecules 2021, 22, 3625–3648.
Originalspracheenglisch
PublikationsstatusVeröffentlicht - 4 Sept. 2023
VeranstaltungPolymer Meeting 15 - Bratislava, Slowakei
Dauer: 4 Sept. 20237 Sept. 2023
https://pm15.sav.sk/

Konferenz

KonferenzPolymer Meeting 15
KurztitelPM15
Land/GebietSlowakei
OrtBratislava
Zeitraum4/09/237/09/23
Internetadresse

Fields of Expertise

  • Advanced Materials Science

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