Functionalized graphene as a gatekeeper for chiral molecules: An alternative concept for chiral separation

Andreas Hauser; Narbe Mardirossian; Julien A. Panetier; Martin Head-Gordon; Alexis T. Bell; Peter Schwerdtfeger

doi:10.1002/anie.201403145

Functionalized graphene as a gatekeeper for chiral molecules: An alternative concept for chiral separation

Andreas Hauser^*, Narbe Mardirossian, Julien A. Panetier, Martin Head-Gordon, Alexis T. Bell, Peter Schwerdtfeger

^*Korrespondierende/r Autor/-in für diese Arbeit

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

We propose a new method of chiral separation using functionalized nanoporous graphene as an example. Computational simulations based on density functional theory show that the attachment of a suitable chiral “bouncer” molecule to the pore rim prevents the passage of the undesired enantiomer while letting its mirror image through.

Originalsprache	englisch
Seiten (von - bis)	9957-9960
Seitenumfang	4
Fachzeitschrift	Angewandte Chemie - International Edition
Jahrgang	53
Ausgabenummer	37
DOIs	https://doi.org/10.1002/anie.201403145
Publikationsstatus	Veröffentlicht - 8 Sept. 2014
Extern publiziert	Ja

ASJC Scopus subject areas

Katalyse
Chemie (insg.)

Fields of Expertise

Advanced Materials Science

Zugriff auf Dokument

10.1002/anie.201403145

Andere Dateien und Links

http://www.scopus.com/inward/record.url?scp=84906948876&partnerID=8YFLogxK

Dieses zitieren

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AU - Panetier, Julien A.

AU - Head-Gordon, Martin

AU - Bell, Alexis T.

AU - Schwerdtfeger, Peter

PY - 2014/9/8

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AB - We propose a new method of chiral separation using functionalized nanoporous graphene as an example. Computational simulations based on density functional theory show that the attachment of a suitable chiral "bouncer" molecule to the pore rim prevents the passage of the undesired enantiomer while letting its mirror image through.

KW - chiral separation

KW - enantiomers

KW - graphene

KW - racemic mixture

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U2 - 10.1002/anie.201403145

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M3 - Article

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