Hierarchical Metal-Organic Framework Films with Controllable Meso/Macroporosity

Renheng Bo; Mahdiar Taheri; Borui Liu; Raffaele Ricco; Hongjun Chen; Heinz Amenitsch; Zelio Fusco; Takuya Tsuzuki; Guihua Yu; Rob Ameloot; Paolo Falcaro; Antonio Tricoli

doi:10.1002/advs.202002368

Hierarchical Metal-Organic Framework Films with Controllable Meso/Macroporosity

Renheng Bo, Mahdiar Taheri, Borui Liu, Raffaele Ricco, Hongjun Chen, Heinz Amenitsch, Zelio Fusco, Takuya Tsuzuki, Guihua Yu, Rob Ameloot, Paolo Falcaro, Antonio Tricoli^*

^*Korrespondierende/r Autor/-in für diese Arbeit

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

The structuring of the metal-organic framework material ZIF-8 as films and membranes through the vapor-phase conversion of ZnO fractal nanoparticle networks is reported. The extrinsic porosity of the resulting materials can be tuned from 4% to 66%, and the film thickness can be controlled from 80 nm to 0.23 mm, for areas >100 cm². Freestanding and pure metal-organic frameworks (MOF) membranes prepared this way are showcased as separators that minimize capacity fading in model Li-S batteries.

Originalsprache	englisch
Aufsatznummer	2002368
Fachzeitschrift	Advanced Science
Jahrgang	7
Ausgabenummer	24
DOIs	https://doi.org/10.1002/advs.202002368
Publikationsstatus	Veröffentlicht - 16 Dez. 2020

ASJC Scopus subject areas

Medizin (sonstige)
Chemische Verfahrenstechnik (insg.)
Werkstoffwissenschaften (insg.)
Biochemie, Genetik und Molekularbiologie (sonstige)
Ingenieurwesen (insg.)
Physik und Astronomie (insg.)

Fields of Expertise

Advanced Materials Science

Zugriff auf Dokument

10.1002/advs.202002368

Andere Dateien und Links

Verknüpfung zur Publikation in Scopus

Poröse Materialien @ Arbeit
Klimant, I., Nidetzky, B., Coclite, A. M., Schennach, R., Sonderegger, B., Resel, R., Würschum, R., Amenitsch, H., Zojer, E., Bergmann, A., Falcaro, P., Borisov, S., Trimmel, G. & Slugovc, C.
1/07/18 → 31/03/22
Projekt: Forschungsprojekt
EU - POPCRYSTAL - Präzise orientierte poröse kristalline Filme und Muster
Falcaro, P.
1/05/18 → 30/04/23
Projekt: Forschungsprojekt
EU - MNEMONIC - Magnetisches Enzymmetall organische Fachwerkzusammensetzung
Ricco, R.
1/11/17 → 30/10/19
Projekt: Forschungsprojekt

Dieses zitieren

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title = "Hierarchical Metal-Organic Framework Films with Controllable Meso/Macroporosity",

abstract = "The structuring of the metal-organic framework material ZIF-8 as films and membranes through the vapor-phase conversion of ZnO fractal nanoparticle networks is reported. The extrinsic porosity of the resulting materials can be tuned from 4% to 66%, and the film thickness can be controlled from 80 nm to 0.23 mm, for areas >100 cm2. Freestanding and pure metal-organic frameworks (MOF) membranes prepared this way are showcased as separators that minimize capacity fading in model Li-S batteries.",

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year = "2020",

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day = "16",

doi = "10.1002/advs.202002368",

language = "English",

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T1 - Hierarchical Metal-Organic Framework Films with Controllable Meso/Macroporosity

AU - Bo, Renheng

AU - Taheri, Mahdiar

AU - Liu, Borui

AU - Ricco, Raffaele

AU - Chen, Hongjun

AU - Amenitsch, Heinz

AU - Fusco, Zelio

AU - Tsuzuki, Takuya

AU - Yu, Guihua

AU - Ameloot, Rob

AU - Falcaro, Paolo

AU - Tricoli, Antonio

PY - 2020/12/16

Y1 - 2020/12/16

N2 - The structuring of the metal-organic framework material ZIF-8 as films and membranes through the vapor-phase conversion of ZnO fractal nanoparticle networks is reported. The extrinsic porosity of the resulting materials can be tuned from 4% to 66%, and the film thickness can be controlled from 80 nm to 0.23 mm, for areas >100 cm2. Freestanding and pure metal-organic frameworks (MOF) membranes prepared this way are showcased as separators that minimize capacity fading in model Li-S batteries.

AB - The structuring of the metal-organic framework material ZIF-8 as films and membranes through the vapor-phase conversion of ZnO fractal nanoparticle networks is reported. The extrinsic porosity of the resulting materials can be tuned from 4% to 66%, and the film thickness can be controlled from 80 nm to 0.23 mm, for areas >100 cm2. Freestanding and pure metal-organic frameworks (MOF) membranes prepared this way are showcased as separators that minimize capacity fading in model Li-S batteries.

KW - 3D structuring

KW - extrinsic porosity

KW - metal-organic frameworks

KW - molecular sieving

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U2 - 10.1002/advs.202002368

DO - 10.1002/advs.202002368

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AN - SCOPUS:85096767784

SN - 2198-3844

VL - 7

JO - Advanced Science

JF - Advanced Science

IS - 24

M1 - 2002368

ER -

Hierarchical Metal-Organic Framework Films with Controllable Meso/Macroporosity

Abstract

ASJC Scopus subject areas

Fields of Expertise

Zugriff auf Dokument

Andere Dateien und Links

Projekte

Poröse Materialien @ Arbeit

EU - POPCRYSTAL - Präzise orientierte poröse kristalline Filme und Muster

EU - MNEMONIC - Magnetisches Enzymmetall organische Fachwerkzusammensetzung

Dieses zitieren