New insights into the selective and systematic preparation of arylgermanium hydrides

Ana Torvisco Gomez; Melanie Wolf; Michael Traxler; Dietrich Gudat; Frank Uhlig

doi:10.1016/j.mencom.2022.01.006

New insights into the selective and systematic preparation of arylgermanium hydrides

Ana Torvisco Gomez^*, Melanie Wolf, Michael Traxler, Dietrich Gudat, Frank Uhlig

^*Korrespondierende/r Autor/-in für diese Arbeit

Institut für Anorganische Chemie (6330)

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

A series of novel arylgermanium hydrides Ar _nGeH ₄ _–n (n = 1–3) and diaryl(chloro)germanium hydrides Ar ₂Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH _4– _n (Ar = 2,5-Me ₂C ₆H ₃, n = 1–3) were characterized by ¹H and ⁷³Ge NMR spectroscopy and single crystal X-ray diffractometry.

Originalsprache	englisch
Seiten (von - bis)	22-24
Seitenumfang	3
Fachzeitschrift	Mendeleev Communications
Jahrgang	32
Ausgabenummer	1
DOIs	https://doi.org/10.1016/j.mencom.2022.01.006
Publikationsstatus	Veröffentlicht - Jan. 2022

ASJC Scopus subject areas

Anorganische Chemie
Allgemeine Chemie

Fields of Expertise

Advanced Materials Science

Zugriff auf Dokument

10.1016/j.mencom.2022.01.006

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Verknüpfung zur Publikation in Scopus

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title = "New insights into the selective and systematic preparation of arylgermanium hydrides",

abstract = "A series of novel arylgermanium hydrides Ar nGeH 4 –n (n = 1–3) and diaryl(chloro)germanium hydrides Ar 2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH 4– n (Ar = 2,5-Me 2C 6H 3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry. ",

keywords = "arylgermanium hydrides, 73Ge NMR spectroscopy, H NMR spectroscopy, aryl(chloro)germanium hydrides, organogermanium compounds, solid-state structures, Ge NMR spectroscopy",

author = "{Torvisco Gomez}, Ana and Melanie Wolf and Michael Traxler and Dietrich Gudat and Frank Uhlig",

year = "2022",

month = jan,

doi = "10.1016/j.mencom.2022.01.006",

language = "English",

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T1 - New insights into the selective and systematic preparation of arylgermanium hydrides

AU - Torvisco Gomez, Ana

AU - Wolf, Melanie

AU - Traxler, Michael

AU - Gudat, Dietrich

AU - Uhlig, Frank

PY - 2022/1

Y1 - 2022/1

N2 - A series of novel arylgermanium hydrides Ar nGeH 4 –n (n = 1–3) and diaryl(chloro)germanium hydrides Ar 2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH 4– n (Ar = 2,5-Me 2C 6H 3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry.

AB - A series of novel arylgermanium hydrides Ar nGeH 4 –n (n = 1–3) and diaryl(chloro)germanium hydrides Ar 2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH 4– n (Ar = 2,5-Me 2C 6H 3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry.

KW - arylgermanium hydrides

KW - 73Ge NMR spectroscopy

KW - H NMR spectroscopy

KW - aryl(chloro)germanium hydrides

KW - organogermanium compounds

KW - solid-state structures

KW - Ge NMR spectroscopy

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DO - 10.1016/j.mencom.2022.01.006

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EP - 24

JO - Mendeleev Communications

JF - Mendeleev Communications

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