Probing the first steps of photoinduced free radical polymerization at water-oil interfaces

Denisa Darvasiová; Zuzana Barberiková; Anna Eibel; Max Schmallegger; Georg Gescheidt; Michal Zalibera; Dmytro Neshchadin

doi:10.1039/c7py01414g

Probing the first steps of photoinduced free radical polymerization at water-oil interfaces

Denisa Darvasiová, Zuzana Barberiková, Anna Eibel, Max Schmallegger, Georg Gescheidt, Michal Zalibera^*, Dmytro Neshchadin

^*Korrespondierende/r Autor/-in für diese Arbeit

Institut für Physikalische und Theoretische Chemie (6350)

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.

Originalsprache	englisch
Seiten (von - bis)	6943-6947
Seitenumfang	5
Fachzeitschrift	Polymer Chemistry
Jahrgang	8
Ausgabenummer	45
DOIs	https://doi.org/10.1039/c7py01414g
Publikationsstatus	Veröffentlicht - 7 Dez. 2017

ASJC Scopus subject areas

Bioengineering
Biochemie
Polymere und Kunststoffe
Organische Chemie

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10.1039/c7py01414g

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abstract = "Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.",

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AU - Darvasiová, Denisa

AU - Barberiková, Zuzana

AU - Eibel, Anna

AU - Schmallegger, Max

AU - Gescheidt, Georg

AU - Zalibera, Michal

AU - Neshchadin, Dmytro

PY - 2017/12/7

Y1 - 2017/12/7

N2 - Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.

AB - Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.

UR - http://www.scopus.com/inward/record.url?scp=85034844827&partnerID=8YFLogxK

U2 - 10.1039/c7py01414g

DO - 10.1039/c7py01414g

M3 - Article

AN - SCOPUS:85034844827

SN - 1759-9954

VL - 8

SP - 6943

EP - 6947

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 45

ER -

Probing the first steps of photoinduced free radical polymerization at water-oil interfaces

Abstract

ASJC Scopus subject areas

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