TY - JOUR
T1 - Quantitative assessment of microstructural changes of hydrated cement blends due to leaching and carbonation, based on statistical analysis of image data
AU - Furat, Orkun
AU - Baldermann, Andre
AU - Baldermann, Claudia
AU - Dietzel, Martin
AU - Schmidt, Volker
PY - 2021/10/4
Y1 - 2021/10/4
N2 - The evolution of the microstructure in corrosive environments plays a key role for the performance and durability of cementitious materials, however, appropriate methods to quantitatively describe microstructural alterations are limited. Here, statistical analysis of microscopic data is used to describe changes in porosity, continuous and individual pore size distributions of reactive cement phases during leaching and carbonation of hydrated cement blends. Therefore, BSE images obtained from (un)damaged areas of the cement blends were segmented using image processing techniques, followed by geometrical characterization and quantitative evaluation of the microstructural response(s). It is shown that the dissolution of portlandite generates a high meso- and macro-porosity (> 100-4000 nm pores), whereas precipitation of C-(A)-S-H and Ca-carbonate polymorphs leads to a densification of the microstructure, i.e., reducing the fine meso- and micro-porosity (< 500 nm pores). Cement blends made with hydraulically active SCMs and chemically poorly reactive carbonate fillers performed better than pure (OPC-based) cement paste.
AB - The evolution of the microstructure in corrosive environments plays a key role for the performance and durability of cementitious materials, however, appropriate methods to quantitatively describe microstructural alterations are limited. Here, statistical analysis of microscopic data is used to describe changes in porosity, continuous and individual pore size distributions of reactive cement phases during leaching and carbonation of hydrated cement blends. Therefore, BSE images obtained from (un)damaged areas of the cement blends were segmented using image processing techniques, followed by geometrical characterization and quantitative evaluation of the microstructural response(s). It is shown that the dissolution of portlandite generates a high meso- and macro-porosity (> 100-4000 nm pores), whereas precipitation of C-(A)-S-H and Ca-carbonate polymorphs leads to a densification of the microstructure, i.e., reducing the fine meso- and micro-porosity (< 500 nm pores). Cement blends made with hydraulically active SCMs and chemically poorly reactive carbonate fillers performed better than pure (OPC-based) cement paste.
KW - Blended cements
KW - Leaching
KW - Microstructure
KW - Statistical image analysis
KW - Supplementary cementitious materials
UR - http://www.scopus.com/inward/record.url?scp=85111582893&partnerID=8YFLogxK
U2 - 10.1016/j.conbuildmat.2021.124370
DO - 10.1016/j.conbuildmat.2021.124370
M3 - Article
AN - SCOPUS:85111582893
SN - 0950-0618
VL - 302
JO - Construction and Building Materials
JF - Construction and Building Materials
M1 - 124370
ER -