A new method to position and functionalize metal-organic framework crystals

Paolo Falcaro, Anita J. Hill, Kate M. Nairn, Jacek Jasieniak, James I. Mardel, Timothy J. Bastow, Sheridan C. Mayo, Michele Gimona, Daniel Gomez, Harold J. Whitfield, Raffaele Ricco, Alessandro Patelli, Benedetta Marmiroli, Heinz Amenitsch, Tobias Colson, Laura Villanova, Dario Buso

Research output: Contribution to journalArticlepeer-review


With controlled nanometre-sized pores and surface areas of thousands of square metres per gram, metal-organic frameworks (MOFs) may have an integral role in future catalysis, filtration and sensing applications. In general, for MOF-based device fabrication, well-organized or patterned MOF growth is required, and thus conventional synthetic routes are not suitable. Moreover, to expand their applicability, the introduction of additional functionality into MOFs is desirable. Here, we explore the use of nanostructured poly-hydrate zinc phosphate (α-hopeite) microparticles as nucleation seeds for MOFs that simultaneously address all these issues. Affording spatial control of nucleation and significantly accelerating MOF growth, these α-hopeite microparticles are found to act as nucleation agents both in solution and on solid surfaces. In addition, the introduction of functional nanoparticles (metallic, semiconducting, polymeric) into these nucleating seeds translates directly to the fabrication of functional MOFs suitable for molecular size-selective applications.
Original languageEnglish
Article number237
Pages (from-to)1-8
JournalNature Communications
Publication statusPublished - 2011

Fields of Expertise

  • Advanced Materials Science

Treatment code (Nähere Zuordnung)

  • Experimental

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