Application of Spectrophotometric Methods in Assessing the Influence of Alkaline Treatment on the Degree of Crosslinking of Cotton Cellulose with BTCA

Olivera Šauperl*, Karin Stana Kleinschek, Bojana Vončina, Majda Sfiligoj Smole, Alenka Majcen le Marechal

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Polycarboxylic acids appear to be the most promising nonformaldehyde crosslinking agents to replace the traditional, mostly formaldehyde-based, compounds. The most effective among these acids is 1,2,3,4- butanetetracarboxylic acid (BTCA). In this study, a comparison was made of the crosslinking effect on mercerized and on unmercerized as well as with different BTCA mass fractions crosslinked cotton fibres using FT-IR spectroscopy, the methylene blue method and water retention determination. The main purpose of the research was to evaluate how the structural changes of mercerized cotton (transformation of cellulose I into cellulose II) influence the crosslinking of cellulose fibres.

Original languageEnglish
Pages (from-to)293-298
Number of pages6
JournalCroatica Chemica Acta
Volume76
Issue number4
Publication statusPublished - 1 Nov 2003
Externally publishedYes

Keywords

  • BTCA
  • Cotton cellulose
  • Crosslinking
  • Mercerization

ASJC Scopus subject areas

  • Chemistry(all)

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