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Abstract
Fuel cells convert chemical energy directly into electrical energy with high efficiency and without pollutants. The decomposition products in the clean exhaust gas caused by the chemical degradation of the membrane of polymer electrolyte fuel cells (PEFCs) can be used to monitor the service life of the cell. For perfluorinated sulfonic acid (PFSA)-based membranes, chemical degradation is investigated via ex situ monitoring of the effluent water. The decomposition of the PFSA backbone, which is part of the polymer electrolyte membrane (PEM), can be detected by the degradation products such as fluoride or fluorinated compounds [1]. There are multiple methods for measuring fluoride in water. We have developed a new method for the simple and precise measurement of fluoride based on the optical change caused by the quenching of a zirconium complex. This method requires only 900 µL of the sample and 100 µL of the complex [2].
We have extended the two fluoride measurement methods, namely fluoride sensitive electrode (FSE) and photometry (PM), to include ion chromatography (IC). This serves as an additional point of comparison with high accuracy and expands the measuring scope to include other ions like sulfate and their potential influence on photometric measurements.
The electrochemical characterization of the materials has been improved by adapted electrochemical impedance spectroscopy (EIS) equivalent circuits, which include a more detailed analysis of the contribution of degradation processes. Linear sweep voltammetry (LSV) was used to measure the gas crossover through the membrane. Cyclic voltammetry provides information about the change in electrochemical surface area. Electrochemical characterizations and fluoride measurements are supplemented by ex situ imaging methods to determine membrane thinning.
We have extended the two fluoride measurement methods, namely fluoride sensitive electrode (FSE) and photometry (PM), to include ion chromatography (IC). This serves as an additional point of comparison with high accuracy and expands the measuring scope to include other ions like sulfate and their potential influence on photometric measurements.
The electrochemical characterization of the materials has been improved by adapted electrochemical impedance spectroscopy (EIS) equivalent circuits, which include a more detailed analysis of the contribution of degradation processes. Linear sweep voltammetry (LSV) was used to measure the gas crossover through the membrane. Cyclic voltammetry provides information about the change in electrochemical surface area. Electrochemical characterizations and fluoride measurements are supplemented by ex situ imaging methods to determine membrane thinning.
Original language | English |
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DOIs | |
Publication status | Published - 31 Mar 2023 |
Event | 244th ECS Meeting - Gothenburg, Sweden Duration: 8 Oct 2023 → 12 Oct 2023 |
Conference
Conference | 244th ECS Meeting |
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Country/Territory | Sweden |
City | Gothenburg |
Period | 8/10/23 → 12/10/23 |
Fields of Expertise
- Mobility & Production
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Dive into the research topics of 'Determination of Membrane Degradation in Polymer Electrolyte Fuel Cells with In-Situ and Ex-Situ Measurements'. Together they form a unique fingerprint.Projects
- 1 Active
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HyTechonomy - Hydrogen Technologies for Sustainable Economies
Hacker, V. (Co-Investigator (CoI)), Schutting, E. (Co-Investigator (CoI)), Hochenauer, C. (Co-Investigator (CoI)), Subotić, V. (Co-Investigator (CoI)), Bodner, M. (Co-Investigator (CoI)), Kuhnert, E. (Co-Investigator (CoI)) & Heidinger, M. (Co-Investigator (CoI))
1/04/21 → 31/03/25
Project: Research project
Activities
- 1 Talk at conference or symposium
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Determination of Membrane Degradation in Polymer Electrolyte Fuel Cells with In-Situ and Ex-Situ Measurements
Heidinger, M. (Speaker), Sandu, D. (Contributor), Hacker, V. (Contributor) & Bodner, M. (Contributor)
10 Oct 2023Activity: Talk or presentation › Talk at conference or symposium › Science to science