Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate

K. N. Singh, Susanna Neuhold, Christa Grogger, V. V. Jouikov

Research output: Contribution to journalArticlepeer-review


Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.
Original languageEnglish
Pages (from-to)1170-1174
JournalRussian Journal of Electrochemistry
Issue number10
Publication statusPublished - 2007

Treatment code (Nähere Zuordnung)

  • Basic - Fundamental (Grundlagenforschung)
  • Experimental


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