Elimination of Bis(trimethylsilyl)stannylene from Tris(trimethylsilyl)stannylated Zirconocene and Hafnocene Chlorides

Roland Fischer*, Christoph Marschner*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Reactions of (Me 3Si) 3SnK with Cp 2MCl 2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp 2M(Cl)SiMe 3 formation.

Original languageEnglish
Pages (from-to)52-53
Number of pages2
JournalMendeleev Communications
Volume32
Issue number1
DOIs
Publication statusPublished - 1 Jan 2022

Keywords

  • Group 4 elements
  • Hafnium
  • Metallocenes
  • Silicon
  • Stannylated compounds
  • Stannylene
  • Tin
  • Zirconium

ASJC Scopus subject areas

  • Chemistry(all)

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