Gas-phase derivation of endohedral metallofullerene by ion/molecule reactions.

Dayong Sun, Ziyang Liu, Xinghua Guo, C. Hao, W. Xu, S. Liu

Research output: Contribution to journalArticlepeer-review

Abstract

Gas phase ion-molecular reactions of endohedral metallofullerenes with the self-chemical ionization ion system of vinyl acetate, benzene and acetone in the ion source of the mass spectrometer have been studied. Several derivatized endohedral metallofullerene cations [M@C82-C2H3O]+, [M2@C80-C2H3O]+, [M@C82-C6H6]+ and [M@C82-CO-CH3]+ are observed as the major products. The experimental results indicate that endohedral metallofullerenes have active gas phase reactivities and can be efficiently derivatized by some small organic cations
Original languageEnglish
Pages (from-to)1461-1477
JournalFullerene Science and Technology
Volume5
Issue number7
DOIs
Publication statusPublished - 1997

Treatment code (Nähere Zuordnung)

  • Basic - Fundamental (Grundlagenforschung)
  • Experimental

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