Generalized indirect fourier transformation as a valuable tool for the structural characterization of aqueous nanocrystalline cellulose suspensions by small angle X-ray scattering

Heike M.A. Ehmann; Stefan Spirk; Aleš Doliška; Tamilselvan Mohan; Walter Gössler; Volker Ribitsch; Majda Sfiligoj-Smole; Karin Stana-Kleinschek

doi:10.1021/la303122b

Generalized indirect fourier transformation as a valuable tool for the structural characterization of aqueous nanocrystalline cellulose suspensions by small angle X-ray scattering

Heike M.A. Ehmann, Stefan Spirk^*, Aleš Doliška, Tamilselvan Mohan, Walter Gössler, Volker Ribitsch, Majda Sfiligoj-Smole, Karin Stana-Kleinschek

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Small angle X-ray scattering (SAXS) is employed to characterize the inner structure and shape of aqueous nanocrystalline cellulose suspensions using the generalized indirect Fourier transformation (GIFT). The use of the GIFT approach provides a single fitting procedure for the determination of intra- and interparticle interactions due to a simultaneous treatment of the form factor P(q) and the structure factor S(q). Moreover, GIFT allows for the determination of particle charges and polydispersity indices. As test material, aqueous nanocrystalline cellulose suspensions (aNCS) prepared by the H ₂SO₄ route have been investigated and characterized (SAXS, dynamic light scattering, zeta potential).

Original language	English
Pages (from-to)	3740-3748
Number of pages	9
Journal	Langmuir
Volume	29
Issue number	11
DOIs	https://doi.org/10.1021/la303122b
Publication status	Published - 19 Mar 2013

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

Fields of Expertise

Advanced Materials Science

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10.1021/la303122b

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Ehmann, H. M. A., Spirk, S., Doliška, A., Mohan, T., Gössler, W., Ribitsch, V., Sfiligoj-Smole, M., & Stana-Kleinschek, K. (2013). Generalized indirect fourier transformation as a valuable tool for the structural characterization of aqueous nanocrystalline cellulose suspensions by small angle X-ray scattering. Langmuir, 29(11), 3740-3748. https://doi.org/10.1021/la303122b

Ehmann, HMA, Spirk, S, Doliška, A, Mohan, T, Gössler, W, Ribitsch, V, Sfiligoj-Smole, M & Stana-Kleinschek, K 2013, 'Generalized indirect fourier transformation as a valuable tool for the structural characterization of aqueous nanocrystalline cellulose suspensions by small angle X-ray scattering', Langmuir, vol. 29, no. 11, pp. 3740-3748. https://doi.org/10.1021/la303122b

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title = "Generalized indirect fourier transformation as a valuable tool for the structural characterization of aqueous nanocrystalline cellulose suspensions by small angle X-ray scattering",

abstract = "Small angle X-ray scattering (SAXS) is employed to characterize the inner structure and shape of aqueous nanocrystalline cellulose suspensions using the generalized indirect Fourier transformation (GIFT). The use of the GIFT approach provides a single fitting procedure for the determination of intra- and interparticle interactions due to a simultaneous treatment of the form factor P(q) and the structure factor S(q). Moreover, GIFT allows for the determination of particle charges and polydispersity indices. As test material, aqueous nanocrystalline cellulose suspensions (aNCS) prepared by the H 2SO4 route have been investigated and characterized (SAXS, dynamic light scattering, zeta potential).",

author = "Ehmann, {Heike M.A.} and Stefan Spirk and Ale{\v s} Doli{\v s}ka and Tamilselvan Mohan and Walter G{\"o}ssler and Volker Ribitsch and Majda Sfiligoj-Smole and Karin Stana-Kleinschek",

year = "2013",

month = mar,

day = "19",

doi = "10.1021/la303122b",

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AU - Ehmann, Heike M.A.

AU - Spirk, Stefan

AU - Doliška, Aleš

AU - Mohan, Tamilselvan

AU - Gössler, Walter

AU - Ribitsch, Volker

AU - Sfiligoj-Smole, Majda

AU - Stana-Kleinschek, Karin

PY - 2013/3/19

Y1 - 2013/3/19

N2 - Small angle X-ray scattering (SAXS) is employed to characterize the inner structure and shape of aqueous nanocrystalline cellulose suspensions using the generalized indirect Fourier transformation (GIFT). The use of the GIFT approach provides a single fitting procedure for the determination of intra- and interparticle interactions due to a simultaneous treatment of the form factor P(q) and the structure factor S(q). Moreover, GIFT allows for the determination of particle charges and polydispersity indices. As test material, aqueous nanocrystalline cellulose suspensions (aNCS) prepared by the H 2SO4 route have been investigated and characterized (SAXS, dynamic light scattering, zeta potential).

AB - Small angle X-ray scattering (SAXS) is employed to characterize the inner structure and shape of aqueous nanocrystalline cellulose suspensions using the generalized indirect Fourier transformation (GIFT). The use of the GIFT approach provides a single fitting procedure for the determination of intra- and interparticle interactions due to a simultaneous treatment of the form factor P(q) and the structure factor S(q). Moreover, GIFT allows for the determination of particle charges and polydispersity indices. As test material, aqueous nanocrystalline cellulose suspensions (aNCS) prepared by the H 2SO4 route have been investigated and characterized (SAXS, dynamic light scattering, zeta potential).

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JO - Langmuir

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ER -

Generalized indirect fourier transformation as a valuable tool for the structural characterization of aqueous nanocrystalline cellulose suspensions by small angle X-ray scattering

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