Hexnuclear cadmium(Ii) cluster constructed from tris(2-methylpyridyl)amine (tpa) and azides

Franz-Andreas Mautner; Roland Fischer; Bailey R. Williams; Salah S. Massoud; Nahed M.H. Salem

doi:10.3390/cryst10040317

Hexnuclear cadmium(Ii) cluster constructed from tris(2-methylpyridyl)amine (tpa) and azides

Franz-Andreas Mautner^*, Roland Fischer, Bailey R. Williams, Salah S. Massoud, Nahed M.H. Salem

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd ₆(TPA) ₄(μ ₃-1,1,3-N ₃) ₄(μ ₂-1,1-N ₃) ₆](ClO ₄) ₂·2H ₂O (1) was isolated and structurally characterized, in which the azide ligands reveal μ-1,1,3- and μ-1,1-N ₃ bridging modes.

Original language	English
Article number	317
Journal	Crystals
Volume	10
Issue number	4
DOIs	https://doi.org/10.3390/cryst10040317
Publication status	Published - Apr 2020

Keywords

bridged azide
cadmium
cluster
luminescence emission
poylnuclear
X-ray

ASJC Scopus subject areas

Condensed Matter Physics
Chemical Engineering(all)
Materials Science(all)
Inorganic Chemistry

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10.3390/cryst10040317Licence: CC BY 4.0

Cite this

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title = "Hexnuclear cadmium(Ii) cluster constructed from tris(2-methylpyridyl)amine (tpa) and azides",

abstract = "A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd 6(TPA) 4(μ 3-1,1,3-N 3) 4(μ 2-1,1-N 3) 6](ClO 4) 2·2H 2O (1) was isolated and structurally characterized, in which the azide ligands reveal μ-1,1,3- and μ-1,1-N 3 bridging modes. ",

keywords = "bridged azide, cadmium, cluster, luminescence emission, poylnuclear, X-ray",

author = "Franz-Andreas Mautner and Roland Fischer and Williams, {Bailey R.} and Massoud, {Salah S.} and Salem, {Nahed M.H.}",

year = "2020",

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doi = "10.3390/cryst10040317",

language = "English",

volume = "10",

journal = "Crystals",

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T1 - Hexnuclear cadmium(Ii) cluster constructed from tris(2-methylpyridyl)amine (tpa) and azides

AU - Mautner, Franz-Andreas

AU - Fischer, Roland

AU - Williams, Bailey R.

AU - Massoud, Salah S.

AU - Salem, Nahed M.H.

PY - 2020/4

Y1 - 2020/4

N2 - A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd 6(TPA) 4(μ 3-1,1,3-N 3) 4(μ 2-1,1-N 3) 6](ClO 4) 2·2H 2O (1) was isolated and structurally characterized, in which the azide ligands reveal μ-1,1,3- and μ-1,1-N 3 bridging modes.

AB - A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd 6(TPA) 4(μ 3-1,1,3-N 3) 4(μ 2-1,1-N 3) 6](ClO 4) 2·2H 2O (1) was isolated and structurally characterized, in which the azide ligands reveal μ-1,1,3- and μ-1,1-N 3 bridging modes.

KW - bridged azide

KW - cadmium

KW - cluster

KW - luminescence emission

KW - poylnuclear

KW - X-ray

UR - http://www.scopus.com/inward/record.url?scp=85083959077&partnerID=8YFLogxK

U2 - 10.3390/cryst10040317

DO - 10.3390/cryst10040317

M3 - Article

SN - 2073-4352

VL - 10

JO - Crystals

JF - Crystals

IS - 4

M1 - 317

ER -

Hexnuclear cadmium(Ii) cluster constructed from tris(2-methylpyridyl)amine (tpa) and azides

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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