Investigation of Gas Diffusion Layer Degradation in Polymer Electrolyte Fuel Cells via Chemical Oxidation

Research output: Contribution to conferenceAbstractpeer-review

Abstract

The gas diffusion layer (GDL) is a key part of the membrane electrolyte assembly and is critical for the transport of fuel, oxygen and water. The GDL is made up of two layers: macroporous substrate (MPS) and microporous layer (MPL) (1). To achieve the hydrophobicity required for water management, the two layers are typically treated with polytetrafluoroethylene (PTFE) (2). In many long-term experiments, it has been observed that GDL degradation, such as carbon corrosion and PTFE loss, leads to a deterioration of water management, conductivity and mass transport (3).To solve this durability problem, a thorough and in-depth understanding of the GDL degradation mechanism is required. In this study, GDLs are subjected to an accelerated stress test to investigate degradation by chemical oxidation. GDLs are soaked in Fenton's reagent for 24 hours. The hydrophobic properties of pristine and soaked GDLs are compared based on contact angle measurements, thermogravimetry and scanning electron microscopy. In addition, the chemical composition of the solutions before and after the immersion test is analyzed using a total organic carbon analyzer and an ion chromatograph. The results show that the hydrophobicity of GDL exposed to Fenton reagent is decreased by 5 and 4 degrees for the MPL and the MPS respectively. Fig 1. depicts a decrease in surface contact angle, which is associated with surface oxidation and PTFE deterioration.

Acknowledgement
This research work is performed under the project AlpeDHues (AlpeDHues / FFG 889328) which is supported by the Austrian Research Promotion Agency (FFG).
References
1. C. Csoklich, R. Steim, F. Marone, T. Schmidt and F. Büchi, ACS Applied Materials & Interfaces, 13, 9908–9918 (2021).
2. A. Ozden, S. Shahgaldi, X. Li and F. Hamdullahpur, Progress in Energy and Combustion Science, 74, 50–102 (2019).
3. Y. Yang, X. Zhou, B. Li and C. Zhang, Applied Energy, 303, 117688 (2021).
Original languageEnglish
Publication statusPublished - 7 Apr 2023
Event244th ECS Meeting - Gothenburg, Sweden
Duration: 8 Oct 202312 Oct 2023

Conference

Conference244th ECS Meeting
Country/TerritorySweden
CityGothenburg
Period8/10/2312/10/23

Fields of Expertise

  • Mobility & Production

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