TY - JOUR
T1 - Miscellaneous dimensional coordination polymers and luminescence emission properties of cadmium(II)-pseudohalide complexes
AU - Mautner, Franz A.
AU - Fischer, Roland C.
AU - Salem, Nahed M.H.
AU - Darbonne, Andre J.
AU - Silhan, Shea L.
AU - Haghighijoo, Zahra
AU - Sahu, Sushant P.
AU - Louka, Febee R.
AU - Massoud, Salah S.
N1 - Funding Information:
This research was financially supported by the Department of Chemistry - University of Louisiana at Lafayette . Also, NMHS and SSM thank Faculty of Science-Alexandria University, Alexandria – Egypt.
Funding Information:
This research was financially supported by the Department of Chemistry - University of Louisiana at Lafayette. Also, NMHS and SSM thank Faculty of Science-Alexandria University, Alexandria ? Egypt. This research received no external funding.
Publisher Copyright:
© 2022 Elsevier B.V.
PY - 2022/5/24
Y1 - 2022/5/24
N2 - Two dimensional classes of coordination polymers: 2D catena-[Cd(Me3en)(µ1,5-dca)2] (1) and catena-[Cd(ampip)(μ1,1-N3)(μ1,3-N3)2] (2) and 1D catena-[Cd(pren)(μ1,1-N3)2] (3) and catena-[Cd(isq)2(μ1,3-NCS)2] (4) and catena-{[Cd6(Me3pipz-H)4(Me3pipz)2(μ1,3-NCS)12][Cd(NCS)6]‧6H2O} (5), where Me3en = N,N,N‘-trimethylethylenediamine, ampip = 1-(2-aminoethyl-piperidine, pren = N-(n-propyl)-ethylenediamine, isq = isoquinoline and Me3pipz = 1-(2-dimethylaminoethyl)-4-methylpiperazine, have been synthesized and structurally characterized. The degree of dimensionality and nuclearity were discussed in relation to the skeletal nature of the coligands and the bridging pseudohalides. The luminescence emission properties of the five complexes Cd(II) together with [Cd(TPA)(N3)2]‧H2O (6), [Cd6(TPA)4(µ1,1,3-N3)4(µ1,1-N3)6](ClO4)2·2H2O (7) and [Zn(TPA)(N3)2]‧H2O (TPA = tris(2-methylpyridyl)amine) were investigated in methanol solution. No detectable or weak FL emission was observed in 1–5 complexes. The FL emission enhancement (λex = 260 nm) in the visible region decreases in the order [Zn(TPA)(N3)2]‧H2O > [Cd(TPA)(N3)2]‧H2O (6) ≥ [Cd6(TPA)4(µ1,1,3-N3)4(µ1,1-N3)6](ClO4)2·2H2O (7) with a red shift in the FL emission of the Cd(II)-TPA compounds.
AB - Two dimensional classes of coordination polymers: 2D catena-[Cd(Me3en)(µ1,5-dca)2] (1) and catena-[Cd(ampip)(μ1,1-N3)(μ1,3-N3)2] (2) and 1D catena-[Cd(pren)(μ1,1-N3)2] (3) and catena-[Cd(isq)2(μ1,3-NCS)2] (4) and catena-{[Cd6(Me3pipz-H)4(Me3pipz)2(μ1,3-NCS)12][Cd(NCS)6]‧6H2O} (5), where Me3en = N,N,N‘-trimethylethylenediamine, ampip = 1-(2-aminoethyl-piperidine, pren = N-(n-propyl)-ethylenediamine, isq = isoquinoline and Me3pipz = 1-(2-dimethylaminoethyl)-4-methylpiperazine, have been synthesized and structurally characterized. The degree of dimensionality and nuclearity were discussed in relation to the skeletal nature of the coligands and the bridging pseudohalides. The luminescence emission properties of the five complexes Cd(II) together with [Cd(TPA)(N3)2]‧H2O (6), [Cd6(TPA)4(µ1,1,3-N3)4(µ1,1-N3)6](ClO4)2·2H2O (7) and [Zn(TPA)(N3)2]‧H2O (TPA = tris(2-methylpyridyl)amine) were investigated in methanol solution. No detectable or weak FL emission was observed in 1–5 complexes. The FL emission enhancement (λex = 260 nm) in the visible region decreases in the order [Zn(TPA)(N3)2]‧H2O > [Cd(TPA)(N3)2]‧H2O (6) ≥ [Cd6(TPA)4(µ1,1,3-N3)4(µ1,1-N3)6](ClO4)2·2H2O (7) with a red shift in the FL emission of the Cd(II)-TPA compounds.
KW - Azide
KW - Cadmium
KW - Dicyanamide
KW - Isothiocyanate
KW - X-Ray, luminescence emission
UR - http://www.scopus.com/inward/record.url?scp=85124831729&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2022.120871
DO - 10.1016/j.ica.2022.120871
M3 - Article
AN - SCOPUS:85124831729
SN - 0020-1693
VL - 535
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
M1 - 120871
ER -