New insights into the selective and systematic preparation of arylgermanium hydrides

Ana Torvisco Gomez; Melanie Wolf; Michael Traxler; Dietrich Gudat; Frank Uhlig

doi:10.1016/j.mencom.2022.01.006

New insights into the selective and systematic preparation of arylgermanium hydrides

Ana Torvisco Gomez^*, Melanie Wolf, Michael Traxler, Dietrich Gudat, Frank Uhlig

^*Corresponding author for this work

Institute of Inorganic Chemistry (6330)

Research output: Contribution to journal › Article › peer-review

Abstract

A series of novel arylgermanium hydrides Ar _nGeH ₄ _–n (n = 1–3) and diaryl(chloro)germanium hydrides Ar ₂Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH _4– _n (Ar = 2,5-Me ₂C ₆H ₃, n = 1–3) were characterized by ¹H and ⁷³Ge NMR spectroscopy and single crystal X-ray diffractometry.

Original language	English
Pages (from-to)	22-24
Number of pages	3
Journal	Mendeleev Communications
Volume	32
Issue number	1
DOIs	https://doi.org/10.1016/j.mencom.2022.01.006
Publication status	Published - Jan 2022

Keywords

arylgermanium hydrides
73Ge NMR spectroscopy
H NMR spectroscopy
aryl(chloro)germanium hydrides
organogermanium compounds
solid-state structures
Ge NMR spectroscopy

ASJC Scopus subject areas

Inorganic Chemistry
General Chemistry

Fields of Expertise

Advanced Materials Science

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10.1016/j.mencom.2022.01.006

Cite this

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title = "New insights into the selective and systematic preparation of arylgermanium hydrides",

abstract = "A series of novel arylgermanium hydrides Ar nGeH 4 –n (n = 1–3) and diaryl(chloro)germanium hydrides Ar 2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH 4– n (Ar = 2,5-Me 2C 6H 3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry. ",

keywords = "arylgermanium hydrides, 73Ge NMR spectroscopy, H NMR spectroscopy, aryl(chloro)germanium hydrides, organogermanium compounds, solid-state structures, Ge NMR spectroscopy",

author = "{Torvisco Gomez}, Ana and Melanie Wolf and Michael Traxler and Dietrich Gudat and Frank Uhlig",

year = "2022",

month = jan,

doi = "10.1016/j.mencom.2022.01.006",

language = "English",

volume = "32",

pages = "22--24",

journal = "Mendeleev Communications",

issn = "0959-9436",

publisher = "Elsevier B.V.",

number = "1",

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TY - JOUR

T1 - New insights into the selective and systematic preparation of arylgermanium hydrides

AU - Torvisco Gomez, Ana

AU - Wolf, Melanie

AU - Traxler, Michael

AU - Gudat, Dietrich

AU - Uhlig, Frank

PY - 2022/1

Y1 - 2022/1

N2 - A series of novel arylgermanium hydrides Ar nGeH 4 –n (n = 1–3) and diaryl(chloro)germanium hydrides Ar 2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH 4– n (Ar = 2,5-Me 2C 6H 3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry.

AB - A series of novel arylgermanium hydrides Ar nGeH 4 –n (n = 1–3) and diaryl(chloro)germanium hydrides Ar 2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH 4– n (Ar = 2,5-Me 2C 6H 3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry.

KW - arylgermanium hydrides

KW - 73Ge NMR spectroscopy

KW - H NMR spectroscopy

KW - aryl(chloro)germanium hydrides

KW - organogermanium compounds

KW - solid-state structures

KW - Ge NMR spectroscopy

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U2 - 10.1016/j.mencom.2022.01.006

DO - 10.1016/j.mencom.2022.01.006

M3 - Article

SN - 0959-9436

VL - 32

SP - 22

EP - 24

JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 1

ER -

New insights into the selective and systematic preparation of arylgermanium hydrides

Abstract

Keywords

ASJC Scopus subject areas

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