Abstract
Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.
Original language | English |
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Pages (from-to) | 6943-6947 |
Number of pages | 5 |
Journal | Polymer Chemistry |
Volume | 8 |
Issue number | 45 |
DOIs | |
Publication status | Published - 7 Dec 2017 |
ASJC Scopus subject areas
- Bioengineering
- Biochemistry
- Polymers and Plastics
- Organic Chemistry