Synthesis and film formation of furfuryl- and maleimido carbonic acid derivatives of dextran

Thomas Elschner; Franziska Obst; Karin Stana Kleinschek; Rupert Kargl; Thomas Heinze

doi:10.1016/j.carbpol.2016.12.038

Synthesis and film formation of furfuryl- and maleimido carbonic acid derivatives of dextran

Thomas Elschner, Franziska Obst, Karin Stana Kleinschek, Rupert Kargl, Thomas Heinze^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Carbonic acid derivatives of dextran possessing furfuryl- and maleimido moieties were synthesized and processed into thin films by spin coating. First, products with different degrees of substitution (DS) of up to 3.0 and substitution patterns were obtained and characterized by NMR- and FTIR spectroscopy, as well as elemental analysis. Thin films possessing maleimide groups were obtained by spin coating of maleimido dextran (furan-protected) and dextran furfuryl carbamate that was converted with bismaleimide. The removal of the protecting group (furan) on the thin film was monitored by QCM-D and compared with gravimetric analysis of the bulk material. Film morphology and wettability were determined by means of AFM and contact angle measurements.

Original language	English
Pages (from-to)	1-9
Number of pages	9
Journal	Carbohydrate Polymers
Volume	161
DOIs	https://doi.org/10.1016/j.carbpol.2016.12.038
Publication status	Published - 1 Apr 2017
Externally published	Yes

Keywords

Dextran
Furfuryl carbamate
Maleimido carbonate
Synthesis
Thin film

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1016/j.carbpol.2016.12.038

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title = "Synthesis and film formation of furfuryl- and maleimido carbonic acid derivatives of dextran",

abstract = "Carbonic acid derivatives of dextran possessing furfuryl- and maleimido moieties were synthesized and processed into thin films by spin coating. First, products with different degrees of substitution (DS) of up to 3.0 and substitution patterns were obtained and characterized by NMR- and FTIR spectroscopy, as well as elemental analysis. Thin films possessing maleimide groups were obtained by spin coating of maleimido dextran (furan-protected) and dextran furfuryl carbamate that was converted with bismaleimide. The removal of the protecting group (furan) on the thin film was monitored by QCM-D and compared with gravimetric analysis of the bulk material. Film morphology and wettability were determined by means of AFM and contact angle measurements.",

keywords = "Dextran, Furfuryl carbamate, Maleimido carbonate, Synthesis, Thin film",

author = "Thomas Elschner and Franziska Obst and {Stana Kleinschek}, Karin and Rupert Kargl and Thomas Heinze",

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doi = "10.1016/j.carbpol.2016.12.038",

language = "English",

volume = "161",

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journal = "Carbohydrate Polymers",

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TY - JOUR

T1 - Synthesis and film formation of furfuryl- and maleimido carbonic acid derivatives of dextran

AU - Elschner, Thomas

AU - Obst, Franziska

AU - Stana Kleinschek, Karin

AU - Kargl, Rupert

AU - Heinze, Thomas

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Carbonic acid derivatives of dextran possessing furfuryl- and maleimido moieties were synthesized and processed into thin films by spin coating. First, products with different degrees of substitution (DS) of up to 3.0 and substitution patterns were obtained and characterized by NMR- and FTIR spectroscopy, as well as elemental analysis. Thin films possessing maleimide groups were obtained by spin coating of maleimido dextran (furan-protected) and dextran furfuryl carbamate that was converted with bismaleimide. The removal of the protecting group (furan) on the thin film was monitored by QCM-D and compared with gravimetric analysis of the bulk material. Film morphology and wettability were determined by means of AFM and contact angle measurements.

AB - Carbonic acid derivatives of dextran possessing furfuryl- and maleimido moieties were synthesized and processed into thin films by spin coating. First, products with different degrees of substitution (DS) of up to 3.0 and substitution patterns were obtained and characterized by NMR- and FTIR spectroscopy, as well as elemental analysis. Thin films possessing maleimide groups were obtained by spin coating of maleimido dextran (furan-protected) and dextran furfuryl carbamate that was converted with bismaleimide. The removal of the protecting group (furan) on the thin film was monitored by QCM-D and compared with gravimetric analysis of the bulk material. Film morphology and wettability were determined by means of AFM and contact angle measurements.

KW - Dextran

KW - Furfuryl carbamate

KW - Maleimido carbonate

KW - Synthesis

KW - Thin film

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U2 - 10.1016/j.carbpol.2016.12.038

DO - 10.1016/j.carbpol.2016.12.038

M3 - Article

C2 - 28189217

AN - SCOPUS:85008195169

SN - 0144-8617

VL - 161

SP - 1

EP - 9

JO - Carbohydrate Polymers

JF - Carbohydrate Polymers

ER -

Synthesis and film formation of furfuryl- and maleimido carbonic acid derivatives of dextran

Abstract

Keywords

ASJC Scopus subject areas

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