TY - JOUR
T1 - Synthesis, crystal structures, spectral and magnetic properties of 1-D polymeric dicyanamido-metal(II) complexes
AU - Mautner, Franz-Andreas
AU - Traber, Magdalena
AU - Fischer, Roland
AU - Massoud, Salah S.
AU - Vicente, Ramon
PY - 2017
Y1 - 2017
N2 - Five new metal(II) dicyanamide (dca) complexes with 4-hydroxymethylpyridine (4-OMP) and 4-methoxypyridine (4-MOP) have been synthesized, [Co(dca)2(4-OMP)2]n (1), [Cu(dca)2(4-OMP)2]n (2), [Cu(dca)2(4-MOP)2]n (3), [Cd(dca)2(4-MOP)2]n (4), [Zn(dca)2(4-MOP)2]n (5) and characterized by IR, UV–Vis spectroscopy and single crystal X-ray diffraction. The isostructural polymeric 1-D complexes feature double µ1,5-bridging dicyanamide ligands and terminal 4-OMP or 4-MOP ligands in trans-conformation around the distorted M(II) octahedra. The magnetic properties of complexes 1 and 2 are reported.
AB - Five new metal(II) dicyanamide (dca) complexes with 4-hydroxymethylpyridine (4-OMP) and 4-methoxypyridine (4-MOP) have been synthesized, [Co(dca)2(4-OMP)2]n (1), [Cu(dca)2(4-OMP)2]n (2), [Cu(dca)2(4-MOP)2]n (3), [Cd(dca)2(4-MOP)2]n (4), [Zn(dca)2(4-MOP)2]n (5) and characterized by IR, UV–Vis spectroscopy and single crystal X-ray diffraction. The isostructural polymeric 1-D complexes feature double µ1,5-bridging dicyanamide ligands and terminal 4-OMP or 4-MOP ligands in trans-conformation around the distorted M(II) octahedra. The magnetic properties of complexes 1 and 2 are reported.
U2 - 10.1016/j.poly.2017.09.004
DO - 10.1016/j.poly.2017.09.004
M3 - Article
SN - 0277-5387
VL - 138
SP - 13
EP - 20
JO - Polyhedron
JF - Polyhedron
ER -