TY - JOUR
T1 - An ideal amplitude window against electric fatigue in BaTiO3-based lead-free piezoelectric materials
AU - Fan, Zhongming
AU - Koruza, Jurij
AU - Rödel, Jürgen
AU - Tan, Xiaoli
N1 - Funding Information:
This work was supported by the National Science Foundation through Grant DMR-1465254 .
Funding Information:
This work was supported by the National Science Foundation through Grant DMR-1465254.
Publisher Copyright:
© 2018 Acta Materialia Inc.
PY - 2018/6/1
Y1 - 2018/6/1
N2 - Electric fatigue has been a vexing issue for Pb(Zr,Ti)O3 ceramics, the material-of-choice for piezoelectric technologies, where higher field amplitudes always lead to a more severe property degradation. Thus, piezoelectric devices must be driven under low electric fields to ensure performance reliability, which results in a low efficiency. In the past decade, the intensive worldwide research on lead-free compositions has identified a few ceramics with piezoelectric properties comparable to those of lead-containing ones. However, their resistance to electric fatigue has not been well studied. In this work, we report an abnormal amplitude dependence of electric fatigue in lead-free piezoelectrics: A BaTiO3-based ceramic suffers fatigue degradation when the field amplitude is low, but exhibits an amplitude window at higher fields with essentially no fatigue. Furthermore, electric-field in-situ transmission electron microscopy (TEM) experiments up to 105 cycles are conducted to clearly reveal that the degradation at low fields is due to the unique single-domain state. We, therefore, have identified an ideal amplitude window with performance at full potential and, at the same time, extremely high reliability for a lead-free piezoelectric ceramic that is promising to replace Pb(Zr,Ti)O3.
AB - Electric fatigue has been a vexing issue for Pb(Zr,Ti)O3 ceramics, the material-of-choice for piezoelectric technologies, where higher field amplitudes always lead to a more severe property degradation. Thus, piezoelectric devices must be driven under low electric fields to ensure performance reliability, which results in a low efficiency. In the past decade, the intensive worldwide research on lead-free compositions has identified a few ceramics with piezoelectric properties comparable to those of lead-containing ones. However, their resistance to electric fatigue has not been well studied. In this work, we report an abnormal amplitude dependence of electric fatigue in lead-free piezoelectrics: A BaTiO3-based ceramic suffers fatigue degradation when the field amplitude is low, but exhibits an amplitude window at higher fields with essentially no fatigue. Furthermore, electric-field in-situ transmission electron microscopy (TEM) experiments up to 105 cycles are conducted to clearly reveal that the degradation at low fields is due to the unique single-domain state. We, therefore, have identified an ideal amplitude window with performance at full potential and, at the same time, extremely high reliability for a lead-free piezoelectric ceramic that is promising to replace Pb(Zr,Ti)O3.
KW - Fatigue
KW - Ferroelectric
KW - In-situ transmission electron microscopy (TEM)
KW - Single-domain
UR - http://www.scopus.com/inward/record.url?scp=85045261335&partnerID=8YFLogxK
U2 - 10.1016/j.actamat.2018.03.067
DO - 10.1016/j.actamat.2018.03.067
M3 - Article
AN - SCOPUS:85045261335
SN - 1359-6454
VL - 151
SP - 253
EP - 259
JO - Acta Materialia
JF - Acta Materialia
ER -