Abstract
The electrolyte surface tension exhibits a characteristic minimum around a salt concentration of 1 mM for all ion types, known as the Jones-Ray effect. We show that a consistent description of the experimental surface tension of salts, bases, and acids is possible by assuming charged impurities in the water with a surface affinity typical for surfactants. Comparison with experimental data yields an impurity concentration in the nanomolar range, well below the typical experimental detection limit. Our modeling reveals salt-screening enhanced impurity adsorption as the mechanism behind the Jones-Ray effect: for very low salt concentration added salt screens the electrostatic repulsion between impurities at the surface, which dramatically increases impurity adsorption and thereby reduces the surface tension.
Originalsprache | englisch |
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Seiten (von - bis) | 189-193 |
Seitenumfang | 5 |
Fachzeitschrift | Journal of Physical Chemistry Letters |
Jahrgang | 9 |
Ausgabenummer | 1 |
DOIs | |
Publikationsstatus | Veröffentlicht - 4 Jan. 2018 |
Extern publiziert | Ja |
ASJC Scopus subject areas
- Allgemeine Materialwissenschaften