Emission Behavior and Aftertreatment of Stationary and Transient Operated Hydrogen Engines

As society moves toward climate neutrality, hydrogen fueled internal combustion engines (H2 ICEs) should be considered as a prime technology. These engines are valued for their robustness, superior lifetimes, manufacturing techniques and characteristics, which are already known from diesel or gaso-line engines. Since an H2 ICE is run on hydrogen (H2), carbon-based emissions are only released on a very low level from the lube oil. Nitrogen oxides (NOx) emissions are de facto the only gaseous pollutant that must be processed by the exhaust aftertreatment system (EAS) of such engines.
This paper provides an overview of the raw exhaust gas emission behavior of a two-liter four-cylinder passenger car engine that is run solely on hydrogen. As already mentioned, the main challenge faced by the EAS is to reduce NOx. Thus, the inspected EAS includes a selective catalytic reduction (SCR) catalyst with ammonia (NH3) as a reductant. The species of NOx was reduced under stationary operation conditions at all of the considered engine load points at an efficiency of at least 98%.
Strategies that could be applied to conduct a load change of an H2 ICE were experimentally investigated. To perform a load change under high performance conditions, H2 ICEs needed to be run on a richer air-fuel mixture than under stationary operation conditions in order to provide enough exhaust enthalpy for the turbocharger. If a richer air-fuel mixture was used, higher NOx emissions were detected, indicating that an EAS is essential for H2 ICEs.
A WLTC and two RDE cycles were investigated to determine their raw and tailpipe exhaust gas emis-sions. By applying a simple AdBlue dosing strategy, the raw NOx exhaust gas emissions from the WLTC could be reduced from 79.9 mg/km to as low as 7.3 mg/km. Carbon-based and secondary emissions such as NH3 and N2O were measured at levels well below 5 mg/km.