Abstract
Direct plasma enhanced-atomic layer deposition (PE-ALD) is adopted for the growth of ZnO on c-Si with native oxide at room temperature. The initial stages of growth both in terms of thickness evolution and crystallization onset are followed ex-situ by a combination of spectroscopic ellipsometry and X-ray based techniques (diffraction, reflectivity, and fluorescence). Differently from the growth mode usually reported for thermal ALD ZnO (i.e., substrate-inhibited island growth), the effect of plasma surface activation resulted in a substrate-enhanced island growth. A transient region of accelerated island formation was found within the first 2 nm of deposition, resulting in the growth of amorphous ZnO as witnessed with grazing incidence X-ray diffraction. After the islands coalesced and a continuous layer formed, the first crystallites were found to grow, starting the layer-by-layer growth mode. High-temperature ALD ZnO layers were also investigated in terms of crystallization onset, showing that layers are amorphous up to a thickness of 3 nm, irrespective of the deposition temperature and growth orientation.
Originalsprache | englisch |
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Aufsatznummer | 291 |
Fachzeitschrift | Crystals |
Jahrgang | 10 |
Ausgabenummer | 4 |
DOIs | |
Publikationsstatus | Veröffentlicht - 10 Apr. 2020 |
ASJC Scopus subject areas
- Physik der kondensierten Materie
- Allgemeine chemische Verfahrenstechnik
- Allgemeine Materialwissenschaften
- Anorganische Chemie
Fields of Expertise
- Advanced Materials Science