TY - JOUR
T1 - Material properties particularly suited to be measured with helium scattering
T2 - selected examples from 2D materials, van der Waals heterostructures, glassy materials, catalytic substrates, topological insulators and superconducting radio frequency materials
AU - Holst, Bodil
AU - Alexandrowicz, Gil
AU - Avidor, Nadav
AU - Benedek, Giorgio
AU - Bracco, Gianangelo
AU - Ernst, Wolfgang E.
AU - Farías, Daniel
AU - Jardine, Andrew P.
AU - Lefmann, Kim
AU - Manson, Joseph R.
AU - Marquardt, Roberto
AU - Artés, Salvador Miret
AU - Sibener, Steven J.
AU - Wells, Justin W.
AU - Tamtögl, Anton
AU - Allison, William
N1 - Funding Information:
This paper is a collected effort with broad participation from the materials characterisation community. This is reflected in the author list, which includes experts from both experimental and theoretical helium atom scattering and helium spin-echo scattering as well as experts from the synchrotron, ARPES and neutron scattering communities. We are grateful for careful readings and discussions with other members of the scattering and scanning probe communities. Particular thanks goes to Robert Feidenhansl, Liv Hornkær and Jeppe V. Lauritsen. Finally we acknowledge the contributions made by many people to the development and refinement of the methods discussed here. Among these we note, in particular, the work of J. Peter Toennies and his co-workers over an extended period of time. Their joint contribution forms the technical and scientific foundation on which recent developments have been built.
Publisher Copyright:
© the Owner Societies 2021.
PY - 2021/4/7
Y1 - 2021/4/7
N2 - Helium Atom Scattering (HAS) and Helium Spin-Echo scattering (HeSE), together helium scattering, are well established, but non-commercial surface science techniques. They are characterised by the beam inertness and very low beam energy (<0.1 eV) which allows essentially all materials and adsorbates, including fragile and/or insulating materials and light adsorbates such as hydrogen to be investigated on the atomic scale. At present there only exist an estimated less than 15 helium and helium spin-echo scattering instruments in total, spread across the world. This means that up till now the techniques have not been readily available for a broad scientific community. Efforts are ongoing to change this by establishing a central helium scattering facility, possibly in connection with a neutron or synchrotron facility. In this context it is important to clarify what information can be obtained from helium scattering that cannot be obtained with other surface science techniques. Here we present a non-exclusive overview of a range of material properties particularly suited to be measured with helium scattering: (i) high precision, direct measurements of bending rigidity and substrate coupling strength of a range of 2D materials and van der Waals heterostructures as a function of temperature, (ii) direct measurements of the electron-phonon coupling constantλexclusively in the low energy range (<0.1 eV, tuneable) for 2D materials and van der Waals heterostructures (iii) direct measurements of the surface boson peak in glassy materials, (iv) aspects of polymer chain surface dynamics under nano-confinement (v) certain aspects of nanoscale surface topography, (vi) central properties of surface dynamics and surface diffusion of adsorbates (HeSE) and (vii) two specific science case examples - topological insulators and superconducting radio frequency materials, illustrating how combined HAS and HeSE are necessary to understand the properties of quantum materials. The paper finishes with (viii) examples of molecular surface scattering experiments and other atom surface scattering experiments which can be performed using HAS and HeSE instruments.
AB - Helium Atom Scattering (HAS) and Helium Spin-Echo scattering (HeSE), together helium scattering, are well established, but non-commercial surface science techniques. They are characterised by the beam inertness and very low beam energy (<0.1 eV) which allows essentially all materials and adsorbates, including fragile and/or insulating materials and light adsorbates such as hydrogen to be investigated on the atomic scale. At present there only exist an estimated less than 15 helium and helium spin-echo scattering instruments in total, spread across the world. This means that up till now the techniques have not been readily available for a broad scientific community. Efforts are ongoing to change this by establishing a central helium scattering facility, possibly in connection with a neutron or synchrotron facility. In this context it is important to clarify what information can be obtained from helium scattering that cannot be obtained with other surface science techniques. Here we present a non-exclusive overview of a range of material properties particularly suited to be measured with helium scattering: (i) high precision, direct measurements of bending rigidity and substrate coupling strength of a range of 2D materials and van der Waals heterostructures as a function of temperature, (ii) direct measurements of the electron-phonon coupling constantλexclusively in the low energy range (<0.1 eV, tuneable) for 2D materials and van der Waals heterostructures (iii) direct measurements of the surface boson peak in glassy materials, (iv) aspects of polymer chain surface dynamics under nano-confinement (v) certain aspects of nanoscale surface topography, (vi) central properties of surface dynamics and surface diffusion of adsorbates (HeSE) and (vii) two specific science case examples - topological insulators and superconducting radio frequency materials, illustrating how combined HAS and HeSE are necessary to understand the properties of quantum materials. The paper finishes with (viii) examples of molecular surface scattering experiments and other atom surface scattering experiments which can be performed using HAS and HeSE instruments.
UR - http://www.scopus.com/inward/record.url?scp=85103941273&partnerID=8YFLogxK
U2 - 10.1039/D0CP05833E
DO - 10.1039/D0CP05833E
M3 - Review article
C2 - 33625410
SN - 1463-9076
VL - 23
SP - 7653
EP - 7672
JO - Physical Chemistry, Chemical Physics
JF - Physical Chemistry, Chemical Physics
IS - 13
ER -