Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

Sumea Klokic; Benedetta Marmiroli; Denys Naumenko; Giovanni Birarda; Simone Dal Zilio; Miriam de J. Velásquez-Hernández; Paolo Falcaro; Lisa Vaccari; Heinz Amenitsch

doi:10.1039/d4ce00221k

Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

Sumea Klokic, Benedetta Marmiroli, Denys Naumenko, Giovanni Birarda, Simone Dal Zilio, Miriam de J. Velásquez-Hernández, Paolo Falcaro, Lisa Vaccari, Heinz Amenitsch^*

^*Korrespondierende/r Autor/-in für diese Arbeit

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage. Herein, by introducing chlorine substituents in an azobenzene-infiltrated Cl-DMOF-1 film structure, a significantly slowed structural response is obtained upon photo-switching of the system.

Originalsprache	englisch
Seiten (von - bis)	2228-2232
Seitenumfang	5
Fachzeitschrift	CrystEngComm
Jahrgang	26
Ausgabenummer	17
DOIs	https://doi.org/10.1039/d4ce00221k
Publikationsstatus	Veröffentlicht - 22 März 2024

ASJC Scopus subject areas

Allgemeine Chemie
Allgemeine Materialwissenschaften
Physik der kondensierten Materie

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10.1039/d4ce00221kLizenz: CC BY-NC 4.0

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abstract = "Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage. Herein, by introducing chlorine substituents in an azobenzene-infiltrated Cl-DMOF-1 film structure, a significantly slowed structural response is obtained upon photo-switching of the system.",

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AU - Klokic, Sumea

AU - Marmiroli, Benedetta

AU - Naumenko, Denys

AU - Birarda, Giovanni

AU - Dal Zilio, Simone

AU - Velásquez-Hernández, Miriam de J.

AU - Falcaro, Paolo

AU - Vaccari, Lisa

AU - Amenitsch, Heinz

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N2 - Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage. Herein, by introducing chlorine substituents in an azobenzene-infiltrated Cl-DMOF-1 film structure, a significantly slowed structural response is obtained upon photo-switching of the system.

AB - Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage. Herein, by introducing chlorine substituents in an azobenzene-infiltrated Cl-DMOF-1 film structure, a significantly slowed structural response is obtained upon photo-switching of the system.

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ER -

Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

Abstract

ASJC Scopus subject areas

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