Abstract
The synthesis, IR spectra and single-crystal structures of two Mn(II) and one Zn(II) azido complexes with halo-substituted pyridine derivative ligands are reported: [Mn(N3)-2(3-Brpy)2(H2O)]2(3-Brpy)2 (1), [Mn(N3)2(3-Brpy)2] n (2) and [Zn(N3)2(3-amino,2-chloropyridine)] n (3) with 3-Brpy = 3-bromopyridine. In the dinuclear Mn(II) complex 1 and polymeric 1D Zn(II) complex 3, di-EO only azido bridges exist, whereas in the polymeric Mn(II) 1D system of 2, a rather less common di-EO/di-EO/di-EE azido bridging sequence has been observed (EO = end-on, EE = end-to-end). The halo-substituted pyridine derivatives act in the three compounds as terminal ligands and in 1 also as solvent molecules.
Originalsprache | englisch |
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Seiten (von - bis) | 319-325 |
Fachzeitschrift | Transition Metal Chemistry |
Jahrgang | 38 |
DOIs | |
Publikationsstatus | Veröffentlicht - 2013 |
Fields of Expertise
- Advanced Materials Science
Treatment code (Nähere Zuordnung)
- Basic - Fundamental (Grundlagenforschung)