Abstract
The synthesis of various porphyrinato group 14 derivatives is known from literature.[1] Such compounds are of interest due to their highly interesting electronical behavior. In case of trans-bis(phenylacetylido)(meso-tetra-phenylporphyrinato)E(IV) only the silicon derivative was known from literature so far.[2]
Here we describe the synthesis of a series of trans-bis(arylacetylido)(meso-tetra-phenylporphyrinato) group 14 derivatives and demonstrate selected properties.
[1] M. Gouterman, F. P. Schwarz, P. D. Smith, D. Dolphin, J. Chem. Phys. 1973, 59, 676-690.
[2] J. Zheng, K. Konishi, T. Aida, Inorg. Chem. 1998, 37, 2591-2594.
Here we describe the synthesis of a series of trans-bis(arylacetylido)(meso-tetra-phenylporphyrinato) group 14 derivatives and demonstrate selected properties.
[1] M. Gouterman, F. P. Schwarz, P. D. Smith, D. Dolphin, J. Chem. Phys. 1973, 59, 676-690.
[2] J. Zheng, K. Konishi, T. Aida, Inorg. Chem. 1998, 37, 2591-2594.
| Originalsprache | deutsch |
|---|---|
| Publikationsstatus | Veröffentlicht - 29 Aug. 2016 |
| Veranstaltung | International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2016) - Pardubice, Tschechische Republik Dauer: 28 Aug. 2016 → 2 Sept. 2016 http://www.gtl2016.cz |
Konferenz
| Konferenz | International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2016) |
|---|---|
| Land/Gebiet | Tschechische Republik |
| Zeitraum | 28/08/16 → 2/09/16 |
| Internetadresse |