The Ground State Dipole Moment of BaI from High Precision Stark Spectroscopy

Wolfgang Ernst; Jörn Kändler; T. Törring

doi:10.1016/0009-2614(86)80065-3

The Ground State Dipole Moment of BaI from High Precision Stark Spectroscopy

Wolfgang Ernst, Jörn Kändler, T. Törring

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

The electric dipole moment of the X2σ+ state of Bal was measured using the molecular-beam laser-microwave double-resonance technique. From the analysis of the splitting and shift of rotational transitions in an electric field, the dipole moment of the vibrational ground state was determined as μ = 5.969(6) D (absolute error of the measurement in parentheses). The dipole moment predicted from an ionic bonding model is 6.14 D.

Originalsprache	englisch
Seiten (von - bis)	243-245
Fachzeitschrift	Chemical Physics Letters
Jahrgang	123
Ausgabenummer	4
DOIs	https://doi.org/10.1016/0009-2614(86)80065-3
Publikationsstatus	Veröffentlicht - 1986
Extern publiziert	Ja

Fields of Expertise

Advanced Materials Science

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10.1016/0009-2614(86)80065-3

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title = "The Ground State Dipole Moment of BaI from High Precision Stark Spectroscopy",

abstract = "The electric dipole moment of the X2σ+ state of Bal was measured using the molecular-beam laser-microwave double-resonance technique. From the analysis of the splitting and shift of rotational transitions in an electric field, the dipole moment of the vibrational ground state was determined as μ = 5.969(6) D (absolute error of the measurement in parentheses). The dipole moment predicted from an ionic bonding model is 6.14 D.",

author = "Wolfgang Ernst and J{\"o}rn K{\"a}ndler and T. T{\"o}rring",

year = "1986",

doi = "10.1016/0009-2614(86)80065-3",

language = "English",

volume = "123",

pages = "243--245",

journal = "Chemical Physics Letters",

issn = "1873-4448",

publisher = "Elsevier B.V.",

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T1 - The Ground State Dipole Moment of BaI from High Precision Stark Spectroscopy

AU - Ernst, Wolfgang

AU - Kändler, Jörn

AU - Törring, T.

PY - 1986

Y1 - 1986

N2 - The electric dipole moment of the X2σ+ state of Bal was measured using the molecular-beam laser-microwave double-resonance technique. From the analysis of the splitting and shift of rotational transitions in an electric field, the dipole moment of the vibrational ground state was determined as μ = 5.969(6) D (absolute error of the measurement in parentheses). The dipole moment predicted from an ionic bonding model is 6.14 D.

AB - The electric dipole moment of the X2σ+ state of Bal was measured using the molecular-beam laser-microwave double-resonance technique. From the analysis of the splitting and shift of rotational transitions in an electric field, the dipole moment of the vibrational ground state was determined as μ = 5.969(6) D (absolute error of the measurement in parentheses). The dipole moment predicted from an ionic bonding model is 6.14 D.

U2 - 10.1016/0009-2614(86)80065-3

DO - 10.1016/0009-2614(86)80065-3

M3 - Article

SN - 1873-4448

VL - 123

SP - 243

EP - 245

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4

ER -

The Ground State Dipole Moment of BaI from High Precision Stark Spectroscopy

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