TY - JOUR
T1 - Tuning the morphology of sputter-deposited platinum catalyst
T2 - From compact layers to dispersed nanoparticles
AU - Sandhya, Athira Lekshmi Mohandas
AU - Pleskunov, Pavel
AU - Bogar, Marco
AU - Xie, Xianxian
AU - Wieser, Philipp Aldo
AU - Orság, Martin
AU - Dinhová, Thu Ngan
AU - Dopita, Milan
AU - Taccani, Rodolfo
AU - Amenitsch, Heinz
AU - Choukourov, Andrei
AU - Matolínová, Iva
AU - Khalakhan, Ivan
N1 - Publisher Copyright:
© 2023 Elsevier B.V.
PY - 2023/8
Y1 - 2023/8
N2 - A comprehensive study on adjusting the morphology of sputter-deposited platinum was performed. Platinum was deposited under various Ar pressure ranging from 0.3 to 3.2 Pa using a conventional magnetron system as well as at 57 Pa using a gas aggregation cluster source integrated into the magnetron sputtering system. The morphology and structure of deposited layers were characterized with a broad portfolio of characterization techniques such as scanning electron microscopy, transmission electron microscopy, grazing incidence small angle X-ray scattering and X-ray diffraction. The results revealed a continuous evolution of the Pt layer morphology from a thin-film-like layer of tightly packed Pt nanoparticles to a deposit composed of dispersed particles of 5-7 nm in size as the Ar pressure increased. The electrochemically active surface area of deposited Pt, as calculated from cyclic voltammograms, increased with deposition pressure from 11.7 m2·gPt−1 to 22.3 m2·gPt−1 and 24 m2·gPt−1 for Pt deposited at 0.3, 3.2 and 57 Pa, respectively. This increase in active sites was reflected in a significant improvement in the mass activity of platinum exemplary confirmed using a methanol electrooxidation reaction.
AB - A comprehensive study on adjusting the morphology of sputter-deposited platinum was performed. Platinum was deposited under various Ar pressure ranging from 0.3 to 3.2 Pa using a conventional magnetron system as well as at 57 Pa using a gas aggregation cluster source integrated into the magnetron sputtering system. The morphology and structure of deposited layers were characterized with a broad portfolio of characterization techniques such as scanning electron microscopy, transmission electron microscopy, grazing incidence small angle X-ray scattering and X-ray diffraction. The results revealed a continuous evolution of the Pt layer morphology from a thin-film-like layer of tightly packed Pt nanoparticles to a deposit composed of dispersed particles of 5-7 nm in size as the Ar pressure increased. The electrochemically active surface area of deposited Pt, as calculated from cyclic voltammograms, increased with deposition pressure from 11.7 m2·gPt−1 to 22.3 m2·gPt−1 and 24 m2·gPt−1 for Pt deposited at 0.3, 3.2 and 57 Pa, respectively. This increase in active sites was reflected in a significant improvement in the mass activity of platinum exemplary confirmed using a methanol electrooxidation reaction.
KW - Electrochemistry
KW - Magnetron sputtering
KW - Nanoparticles
KW - Platinum catalyst
KW - Thin film
UR - http://www.scopus.com/inward/record.url?scp=85163012883&partnerID=8YFLogxK
U2 - 10.1016/j.surfin.2023.103079
DO - 10.1016/j.surfin.2023.103079
M3 - Article
AN - SCOPUS:85163012883
SN - 2468-0230
VL - 40
JO - Surfaces and Interfaces
JF - Surfaces and Interfaces
M1 - 103079
ER -