Radical anions of azo-compounds – topologies mirrored by 14N hyperfine coupling constants

Knaipp, K. (Speaker)
Gescheidt-Demner, G. (Contributor)

Institute of Physical and Theoretical Chemistry (6350)
Institute of Chemistry and Technology of Biobased Systems (6430)

Activity: Talk or presentation › Talk at conference or symposium › Science to science

Description

We will report on the electrochemistry of bridged azobenzenes connected with EPR and ENDOR experiments of their radical anions. These experiments underline that the 14N hyperfine coupling constant is a key parameter for describing the topology of the radical anions. I will present the relationship between this parameter, orbital hybridization, and electron delocalization.

Period	7 May 2023
Event title	XXVIII International EPR Seminar
Event type	Conference
Location	Mönichwald, AustriaShow on map
Degree of Recognition	International