Selective Chlorination of Germanium Hydrides

Thomas Hafner, Ana Torvisco Gomez, Michael Traxler, Melanie Wolf, Frank Uhlig*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Methods for the selective chlorination of organogermylhydrides are given by the selective functionalization of organogermylhydrides of types R 3GeH, R 2GeH 2 and RGeH 3 (R = alkyl, aryl). The use of trichloroisocyanuric acid (TCCA) allows the direct conversion of Ge-H functions into their monochlorinated derivatives R 2Ge(Cl)H and RGe(Cl)H 2.

Original languageEnglish
Article number10.1002/zaac.202000318
Pages (from-to)1876-1881
Number of pages6
JournalZeitschrift für Anorganische und Allgemeine Chemie
Volume646
Issue number23-24
DOIs
Publication statusPublished - 31 Dec 2020

Keywords

  • Inorganic Chemistry
  • Selective Chlorination
  • Monochlorination
  • Selective chlorination
  • Trichloroisocyanuric acid (TCCA)
  • Organo(chloro)germylhydrides
  • Trifluoromethylsulfonic acid

ASJC Scopus subject areas

  • Inorganic Chemistry

Fields of Expertise

  • Advanced Materials Science

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