Selective Chlorination of Germanium Hydrides

Thomas Hafner; Ana Torvisco Gomez; Michael Traxler; Melanie Wolf; Frank Uhlig

doi:10.1002/zaac.202000318

Selective Chlorination of Germanium Hydrides

Thomas Hafner, Ana Torvisco Gomez, Michael Traxler, Melanie Wolf, Frank Uhlig^*

^*Corresponding author for this work

Institute of Inorganic Chemistry (6330)

Research output: Contribution to journal › Article › peer-review

Abstract

Methods for the selective chlorination of organogermylhydrides are given by the selective functionalization of organogermylhydrides of types R ₃GeH, R ₂GeH ₂ and RGeH ₃ (R = alkyl, aryl). The use of trichloroisocyanuric acid (TCCA) allows the direct conversion of Ge-H functions into their monochlorinated derivatives R ₂Ge(Cl)H and RGe(Cl)H ₂.

Original language	English
Article number	10.1002/zaac.202000318
Pages (from-to)	1876-1881
Number of pages	6
Journal	Zeitschrift für Anorganische und Allgemeine Chemie
Volume	646
Issue number	23-24
DOIs	https://doi.org/10.1002/zaac.202000318
Publication status	Published - 31 Dec 2020

Keywords

Inorganic Chemistry
Selective Chlorination
Monochlorination
Selective chlorination
Trichloroisocyanuric acid (TCCA)
Organo(chloro)germylhydrides
Trifluoromethylsulfonic acid

ASJC Scopus subject areas

Inorganic Chemistry

Fields of Expertise

Advanced Materials Science

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10.1002/zaac.202000318Licence: CC BY 4.0

Cite this

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title = "Selective Chlorination of Germanium Hydrides",

abstract = "Methods for the selective chlorination of organogermylhydrides are given by the selective functionalization of organogermylhydrides of types R 3GeH, R 2GeH 2 and RGeH 3 (R = alkyl, aryl). The use of trichloroisocyanuric acid (TCCA) allows the direct conversion of Ge-H functions into their monochlorinated derivatives R 2Ge(Cl)H and RGe(Cl)H 2. ",

keywords = "Inorganic Chemistry, Selective Chlorination, Monochlorination, Selective chlorination, Trichloroisocyanuric acid (TCCA), Organo(chloro)germylhydrides, Trifluoromethylsulfonic acid",

author = "Thomas Hafner and {Torvisco Gomez}, Ana and Michael Traxler and Melanie Wolf and Frank Uhlig",

year = "2020",

month = dec,

day = "31",

doi = "10.1002/zaac.202000318",

language = "English",

volume = "646",

pages = "1876--1881",

journal = "Zeitschrift f{\"u}r Anorganische und Allgemeine Chemie",

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T1 - Selective Chlorination of Germanium Hydrides

AU - Hafner, Thomas

AU - Torvisco Gomez, Ana

AU - Traxler, Michael

AU - Wolf, Melanie

AU - Uhlig, Frank

PY - 2020/12/31

Y1 - 2020/12/31

N2 - Methods for the selective chlorination of organogermylhydrides are given by the selective functionalization of organogermylhydrides of types R 3GeH, R 2GeH 2 and RGeH 3 (R = alkyl, aryl). The use of trichloroisocyanuric acid (TCCA) allows the direct conversion of Ge-H functions into their monochlorinated derivatives R 2Ge(Cl)H and RGe(Cl)H 2.

AB - Methods for the selective chlorination of organogermylhydrides are given by the selective functionalization of organogermylhydrides of types R 3GeH, R 2GeH 2 and RGeH 3 (R = alkyl, aryl). The use of trichloroisocyanuric acid (TCCA) allows the direct conversion of Ge-H functions into their monochlorinated derivatives R 2Ge(Cl)H and RGe(Cl)H 2.

KW - Inorganic Chemistry

KW - Selective Chlorination

KW - Monochlorination

KW - Selective chlorination

KW - Trichloroisocyanuric acid (TCCA)

KW - Organo(chloro)germylhydrides

KW - Trifluoromethylsulfonic acid

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U2 - 10.1002/zaac.202000318

DO - 10.1002/zaac.202000318

M3 - Article

SN - 1521-3749

VL - 646

SP - 1876

EP - 1881

JO - Zeitschrift für Anorganische und Allgemeine Chemie

JF - Zeitschrift für Anorganische und Allgemeine Chemie

IS - 23-24

M1 - 10.1002/zaac.202000318

ER -

Selective Chlorination of Germanium Hydrides

Abstract

Keywords

ASJC Scopus subject areas

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Access to Document

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