Sequential dual-curing of electron-deficient olefins and alcohols relying on oxa-Michael addition and anionic polymerization

Susanne Maria Fischer; Johanna Uher; Viktor Schallert; Christian Slugovc

Sequential dual-curing of electron-deficient olefins and alcohols relying on oxa-Michael addition and anionic polymerization

Susanne Maria Fischer, Johanna Uher, Viktor Schallert, Christian Slugovc

Institute for Chemistry and Technology of Materials (6380)

Research output: Contribution to conference › Poster › peer-review

Abstract

Herein, we report the preparation of crosslinked polymers from off-stoichiometric oxa-Michael formulations via a self-limiting base-catalyzed reaction between difunctional Michael acceptors and substoichiometric amounts of diols, followed by anionic polymerization of the remaining vinyl groups. The properties of the resulting polymers can be easily tuned by varying the amount of diols. The polymers also exhibit self healing properties [1].

References
[1] Fischer S. M., Schallert V., Uher J. M., Slugovc C. Polym. Chem. 2023, 14, 1081-1084.

Original language	English
Publication status	Published - 4 Sept 2023
Event	Polymer Meeting 15 - Bratislava, Slovakia Duration: 4 Sept 2023 → 7 Sept 2023 https://pm15.sav.sk/

Conference

Conference	Polymer Meeting 15
Abbreviated title	PM15
Country/Territory	Slovakia
City	Bratislava
Period	4/09/23 → 7/09/23
Internet address	https://pm15.sav.sk/

Fields of Expertise

Advanced Materials Science

CD-Laboratory for Organo-Catalysis in Polymerization
Slugovc, C.
1/07/19 → 30/06/26
Project: Research project

Cite this

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title = "Sequential dual-curing of electron-deficient olefins and alcohols relying on oxa-Michael addition and anionic polymerization",

abstract = "Herein, we report the preparation of crosslinked polymers from off-stoichiometric oxa-Michael formulations via a self-limiting base-catalyzed reaction between difunctional Michael acceptors and substoichiometric amounts of diols, followed by anionic polymerization of the remaining vinyl groups. The properties of the resulting polymers can be easily tuned by varying the amount of diols. The polymers also exhibit self healing properties [1].References [1] Fischer S. M., Schallert V., Uher J. M., Slugovc C. Polym. Chem. 2023, 14, 1081-1084.",

author = "Fischer, {Susanne Maria} and Johanna Uher and Viktor Schallert and Christian Slugovc",

year = "2023",

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day = "4",

language = "English",

note = "Polymer Meeting 15, PM15 ; Conference date: 04-09-2023 Through 07-09-2023",

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TY - CONF

T1 - Sequential dual-curing of electron-deficient olefins and alcohols relying on oxa-Michael addition and anionic polymerization

AU - Fischer, Susanne Maria

AU - Uher, Johanna

AU - Schallert, Viktor

AU - Slugovc, Christian

PY - 2023/9/4

Y1 - 2023/9/4

N2 - Herein, we report the preparation of crosslinked polymers from off-stoichiometric oxa-Michael formulations via a self-limiting base-catalyzed reaction between difunctional Michael acceptors and substoichiometric amounts of diols, followed by anionic polymerization of the remaining vinyl groups. The properties of the resulting polymers can be easily tuned by varying the amount of diols. The polymers also exhibit self healing properties [1].References [1] Fischer S. M., Schallert V., Uher J. M., Slugovc C. Polym. Chem. 2023, 14, 1081-1084.

AB - Herein, we report the preparation of crosslinked polymers from off-stoichiometric oxa-Michael formulations via a self-limiting base-catalyzed reaction between difunctional Michael acceptors and substoichiometric amounts of diols, followed by anionic polymerization of the remaining vinyl groups. The properties of the resulting polymers can be easily tuned by varying the amount of diols. The polymers also exhibit self healing properties [1].References [1] Fischer S. M., Schallert V., Uher J. M., Slugovc C. Polym. Chem. 2023, 14, 1081-1084.

M3 - Poster

T2 - Polymer Meeting 15

Y2 - 4 September 2023 through 7 September 2023

ER -

Sequential dual-curing of electron-deficient olefins and alcohols relying on oxa-Michael addition and anionic polymerization

Abstract

Conference

Fields of Expertise

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Projects

CD-Laboratory for Organo-Catalysis in Polymerization

Cite this