Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate

K. N. Singh; Susanna Neuhold; Christa Grogger; V. V. Jouikov

doi:10.1134/S1023193507100102

Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate

K. N. Singh, Susanna Neuhold, Christa Grogger, V. V. Jouikov

Institut für Anorganische Chemie (6330)

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.

Originalsprache	englisch
Seiten (von - bis)	1170-1174
Fachzeitschrift	Russian Journal of Electrochemistry
Jahrgang	43
Ausgabenummer	10
DOIs	https://doi.org/10.1134/S1023193507100102
Publikationsstatus	Veröffentlicht - 2007

Treatment code (Nähere Zuordnung)

Basic - Fundamental (Grundlagenforschung)
Experimental

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10.1134/S1023193507100102

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title = "Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate",

abstract = "Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.",

author = "Singh, {K. N.} and Susanna Neuhold and Christa Grogger and Jouikov, {V. V.}",

year = "2007",

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AU - Neuhold, Susanna

AU - Grogger, Christa

AU - Jouikov, V. V.

PY - 2007

Y1 - 2007

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AB - Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.

U2 - 10.1134/S1023193507100102

DO - 10.1134/S1023193507100102

M3 - Article

SN - 1608-3342

VL - 43

SP - 1170

EP - 1174

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

IS - 10

ER -

Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate

Abstract

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